PIERCE AND STEVENS CHEMICAL CORP. -- BARGE ALL PURPOSE CEMENT -- 8040-01-197-4186 
=====================  Product Identification  =====================

Product ID:BARGE ALL PURPOSE CEMENT
MSDS Date:02/18/1989
FSC:8040
NIIN:01-197-4186
=== Responsible Party ===
Company Name:PIERCE AND STEVENS CHEMICAL CORP.
Address:710 OHIO ST
City:BUFFALO
State:NY
ZIP:14203-3112
Country:US
Info Phone Num:718-856-4910
Emergency Phone Num:718-856-4910
CAGE:EO220
=== Contractor Identification ===
Company Name:FRANKFORD LEATHER CO
CAGE:7K308
Company Name:PIERCE & STEVENS
Box:City:BUFFALO
State:NY
ZIP:14240
Country:US
Phone:716-856-4910
CAGE:77282
Company Name:PIERCE AND STEVENS CHEMICAL CORP.
Address:710 OHIO ST.
Box:1092
City:BUFFALO
State:NY
ZIP:14240
Country:US
Phone:718-958-4910
CAGE:EO220

=============  Composition/Information on Ingredients  =============

Ingred Name:TOLUENE  (SARA III)
CAS:108-88-3
RTECS #:XS5250000
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:ETHYL ACETATE  (SARA III)
CAS:141-78-6
RTECS #:AH5425000
OSHA PEL:400 PPM
ACGIH TLV:400 PPM; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:NAPHTHA (PETROLEUM SPIRITS OR BENZIN)
CAS:8030-30-6
RTECS #:SE7555000
OSHA PEL:100 PPM

Ingred Name:SILICA, CRYSTALLINE - QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293

=====================  Hazards Identification  =====================

Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:YES	 OSHA:NO
Health Hazards Acute and Chronic:REPEATED EXPOSURE TO CRYSTALLINE
    SILICA MAY CAUSE PNEUMOCONIOSIS, A PROGRESSIVELY DISABLING LUNG
    DISEASE. REPEATED OVEREXPOSURE TO TOLUENE MAY CAUSE LIVER DAMAGE.
Explanation of Carcinogenicity:LISTED BY IARC AS "PROBABLY CARCINOGENIC
    TO HUMANS WITH LIMITED EVIDENCE"
Effects of Overexposure:MOSE OR THROAT IRRITATION, CENTRAL NERVOUS
    SYSTEM DEPRESSION, HEADACHE, DIZZINESS, NAUSEA, VOMITING.
    ASPIRATION MATERIAL INTO LUNG MAY CAUSE CHEMICAL PNEUMONITIS WHICH
    MAY BE FATAL.
Medical Cond Aggravated by Exposure:PREXISTING RESPIRATORY CONDITIONS
    MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA.

=======================  First Aid Measures  =======================

First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
    GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
    FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION.
    SKIN:REMOVE  CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF
    IRRITATION PERSISTS, GET MEDICAL ADVICE.  INGESTION:DO NOT INDUCE
    VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE
    MEDICAL ATTENTION.

=====================  Fire Fighting Measures  =====================

Flash Point Method:SCC
Flash Point:25F/-3.8C
Extinguishing Media:USE CLASS B EXTINGUISHERS: CARBON DIOXIDE, ALCOHOL
    FOAM. POLYMER FOAM IS PREFERRED DOR LARGE FIRES.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SELF-CONTAINED
    BREATHING APPARATUS. WATER MAY BE INEFFECTIVE BUT MAY BE USED TO
    COOL EXPOSED CONTAINERS TO PREVENT PRESSURE BUILDUP.
Unusual Fire/Explosion Hazard:DURING EMERGENCY CONDITIONS, OVEREXPOSURE
    TO DECOMPOSTION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY
    NOT BE APPARENT. OBTAIN MEDICAL ATTEMTION.

==================  Accidental Release Measures  ==================

Spill Release Procedures:SMALL SPILL: WIPE/SOAK UP WITH PAPER TOWEL OR
    INERT ABSORBANT. PUT IN DISPOSAL CONTAINER. REMOVE RESIDUE WITH
    WATER. LARGE SPILL: EVACUATE AND VENTILATE AREA. IF POSSIBLE, STOP
    LEAK. DIKE TO RETAIN RU N OFF. VACUUM UP FREE LIQUID. ABSORB/WASH
    RESIDUE.
Neutralizing Agent:NOT APPLICABLE.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DO NOT STORE ABOVE 95 DEGREES F. STORE
    LARGE QUANTITIES IN COMPLIANCE WITH OSHA 29CFR1910.106.
Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID
    PROLONGED OR REPEATED BREATHING OF VAPOR. EMPTY CONTAINERS MUST NOT
    BE WASHED AND REUSED FOR ANY PURPOSE. CONTAINERS SHOULD BE GROUNDED
    AND BONDED. D O NOT WELD,BRAZE OR CUT ON EMPTY CONTAIN

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
    EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED ORGANIC VAPOR
    CARTRIDGE AND DUST/MIST PRE-FILTER RESPIRATORS AS PER CURRENT 29
    CFR 1910.134, INSTRUCTIONS/ WARNINGS AND NIOSH-RESPIRATOR
    SELECTION.
Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE.
    LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED.
Protective Gloves:RUBBER GLOVES.
Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
    INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
    RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
    FOOTWEAR.
Supplemental Safety and Health

==================  Physical/Chemical Properties  ==================

HCC:F2
Boiling Pt:=75.6C, 168.F
B.P. Text:168-475F
Vapor Density:> 1
Spec Gravity:0.91
Appearance and Odor:LIQUID.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT AND SOURCES OF
    IGNITION.
Hazardous Decomposition Products:SMOKE,CARBON MONOXIDE AND CARBON
    DIOXIDE; IN ADDITION, HYDROGEN CHLORIDE, CHLORINE MAY BE GENERATED.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
    APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.

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