GRACE W R AND CO DAVISON CHEMICAL DIV -- SILICA GEL -- 6850-01-036-9625
===================== Product Identification ===================== Product ID:SILICA GEL MSDS Date:04/03/1991 FSC:6850 NIIN:01-036-9625 === Responsible Party === Company Name:GRACE W R AND CO DAVISON CHEMICAL DIV Address:10 E BALTIMORE STREET Box:2117 City:BALTIMORE State:MD ZIP:21202-1630 Country:US Info Phone Num:301-659-9000 Emergency Phone Num:301-659-9000 CAGE:0NAV2 === Contractor Identification === Company Name:GRACE W R AND CO Address:919 18TH ST NW City:WASHINGTON State:DC ZIP:20006 Country:US Phone:410-659-9000 CAGE:0NAV2 Company Name:W R GRACE & CO. DAVISON CHEMICAL DIVISION Address:10 E BALTIMORE STREET Box:2117 City:BALTIMORE State:MD ZIP:21202-1630 Country:US Phone:410-659-9000 CAGE:16210 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA GEL CAS:63231-67-4 RTECS #:VV7322000 Fraction by Wt: 100% Other REC Limits:NONE SPECIFIED OSHA PEL:80 MG/M3 / % SIO2 ACGIH TLV:10 MG/M3 Ingred Name:UNIDENTIFIED COMPONENTS Fraction by Wt: 01.0% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE, SKIN & RESPIRATORY TRACT IRRITATION. CHRONIC: THE DRYING ACTION OF THIS MATERIAL CAN CAUSE IRRITATION OF THE MUCOUS MEMBRANES OF THE NOSE AND THROAT AND IRRITATION OF THE SKIN. AVOID PROLO NGED BREATHING OF THE DUST OR CONTACT OF DUST WITH THE SKIN. Explanation of Carcinogenicity:THIS PRODUCT AND ITS COMPONENTS ARE NOT LISTED ON THE IARC, NTP OR OSHA CARCINOGENS LISTS. Effects of Overexposure:MAY CAUSE EYE, SKIN & RESPIRATORY TRACT IRRITATION. Medical Cond Aggravated by Exposure:MANUFACTURER KNOWS OF NO MEDICAL CONDITIONS ABNORMALLY AGGRAVATED BY EXPOSURE TO SILICA GEL. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY WASH FROM EYES WITH LARGE AMOUNTS OF WATER, OCCASIONALLY LIFTING THE UPPER & LOWER EYE LIDS. IF IRRITATION OCCURS AND PERSISTS, SEEK MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER . INGESTION: MATERIAL WILL PASS THROUGHTHE BODY NORMALLY. INHALATION: REMOVE TO FRESH AIR. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL AS APPROPRIATE FOR SURROUNDINGS. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP OR VACUUM UP OR FLUSH TO SEWER. Neutralizing Agent:NONE REQUIRED ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID PROLONGED BREATHING OF THE DUST OR CONTACT OF DUST WITH THE SKIN. WHEN HANDLING, WEAR LONG SLEEVES AND CLOSE- WEAVE COTTON GLOVES WITH WRISTBAND Other Precautions:WEAR GOGGLES IF DUST CAUSES EYE DISCOMFORT. WEAR A PROPERLY FITTED NIOSH-APPROVED DUST RESPIRATOR FOR DUSTY CONDITIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A PROPERLY FITTED NIOSH/MSHA APPROVED DUST RESPIRATOR IF CONDITIONS ARE DUSTY. Ventilation:MECHANICAL(GENERAL) VENTILATION IS USUALLY ADEQUATE TO MAINTAIN DUST LEVELS BELOW TLV FOR NUISANCE DUST. Protective Gloves:CLOSE-WEAVE COTTON WITH TIGHT WRISTBANDS Eye Protection:GOGGLES FOR DUSTY CONDITIONS Other Protective Equipment:LONG SLEEVED WORK CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING, DRINKING OR SMOKING. VACUUM UP ANY DUST. LAUNDER CLOTHING BEFORE REUSE. Supplemental Safety and Health SILICA GEL IS A SYNTHETIC AMORPHOUS SILICA NOT TO BE CONFUSED WITH CRYSTALLINE SILICA. EPIDEMIOLOGICAL STUDIES INDICATE LOW POTENTIAL FOR ADVERSE HEALTH EFFECTS. SILICA GEL IS CONSIDERED TO BE A NUISA NCE DUST. IN THE ACTIVATED FORM, SILICAGEL ACTS AS A DESICCANT & CAN CAUSE A DRYING IRRITATION OF THE MUCOUS MEMBRANES. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:2.1 pH:3.5-8 Solubility in Water:INSOLUBLE Appearance and Odor:DRY WHITE GRANULES, BEADS OR POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS WITH HYDROGEN FLUORIDE (HF) Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN AN APPROVED LANDFILL ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS. COVER PROMPTLY TO AVOID BLOWING DUST. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.