MATHESON TRI-GAS, INC. -- P-XYLENE -- -
===================== Product Identification ===================== Product ID:P-XYLENE MSDS Date:Jan 24 1989 Kit Part:=== Responsible Party === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 Chemtrec Ind/Phone:18004249300 === Contractor Identification === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST Box:City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. Address:530 WATSON STREET Box:City:WHITBY State:ZIP:L1N 5R9 Country:ONTARIO, CANADA Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:P-XYLENE CAS:106-42-3 Fraction by Wt: 100.0% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:No OSHA:No Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: irritation, low body temperature, ringing in the ears, nausea, vomiting, stomach pain, headache, drowsiness, symptoms of drunkenness, visual disturbances, lung congestion, kidney damage, liver damage, coma LONG TERM EXPOSURE: tingling sensation, menstrual disorders, infertility, reproductive effects, convulsions SKIN CONTACT: SHORT TERM EXPOSURE: irritation, blisters LONG TERM EXPOSURE: rash EYE CONTACT: SHORT TERM EXPOSURE: irritation (possibly severe), tearing LONG TERM EXPOSURE: blurred vision INGESTION: SHORT TERM EXPOSURE: digestive disorders, symptoms of drunkenness, lung congestion, kidney damage, liver damage LONG TERM EXPOSURE: reproductive effects Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. NOTE TO PHYSICIAN: For inhalation, consider oxygen. For ingestion, consider gastric lavage. ===================== Fire Fighting Measures ===================== Flash Point:81 F (27 C) (CC) Autoignition Temp:982 F (528 C) Lower Limits:1.1% Upper Limits:7.0% Extinguishing Media:regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray. Fire Fighting Procedures:Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation radius: 800 meters (1/2 mile). Water may be ineffective. Unusual Fire/Explosion Hazard:Severe fire hazard. Vapor/air mixtures are explosive above flash point. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Electrostatic discharges may be generated by flow or agitation resulting in ignition or explosion. ================== Accidental Release Measures ================== Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Protect from physical damage. Store outside or in a detached building. Store with flammable liquids. Keep separated from incompatible substances. Keep separated from incompatible substances. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. 900 ppm Any chemical cartridge respirator with organic vapor cartridge(s). Any powered, air-purifying respirator with organic vapor cartridge(s). Any supplied-air respirator. Any self-contained breathing apparatus with a full facepiece. Escape - Any air-purifying respirator with a full facepiece and an organic vapor canister. Any appropriate escape-type, self-contained breathing apparatus. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. Protective Gloves:Wear appropriate chemical resistant gloves. Eye Protection:Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:Wear appropriate chemical resistant clothing. Supplemental Safety and Health P-XYLENE: XYLENE: 100 ppm (435 mg/m3) OSHA TWA 150 ppm (651 mg/m3) OSHA STEL (vacated by 58 FR 35338, June 30, 1993) 100 ppm ACGIH TWA 150 ppm ACGIH STEL 100 ppm (435 mg/m3) NIOSH recommended TWA 10 hour(s) 150 ppm (655 mg/m3) NIOSH recommended STEL ================== Physical/Chemical Properties ================== Boiling Pt:280 F (138 C) Melt/Freeze Pt:55 F (13 C) Vapor Pres:8.6 mmHg @ 25 C Vapor Density:3.7 Spec Gravity:0.8611 pH:Not available Evaporation Rate & Reference:0.7 (butyl acetate=1) Solubility in Water:insoluble Appearance and Odor:PHYSICAL STATE:liquid APPEARANCE:clear COLOR:colorless ODOR:sweet odor Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:Stable at normal temperatures and pressure. Stability Condition to Avoid:Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Keep out of water supplies and sewers. Hazardous Decomposition Products:Thermal decomposition products: oxides of carbon Thermal decomposition products: oxides of carbon Conditions to Avoid Polymerization:Will not polymerize. =================== Toxicological Information =================== Toxicological Information:P-XYLENE: TOXICITY DATA: 4550 ppm/4 hour(s) inhalation-rat LC50; 5 gm/kg oral-rat LD50 LOCAL EFFECTS: Irritant: inhalation, skin, eye ACUTE TOXICITY LEVEL: Moderately Toxic: inhalation, ingestion TARGET ORGANS: central nervous system REPRODUCTIVE EFFECTS DATA: Available. ADDITIONAL DATA: Alcohol may enhance the toxic effects. Stimulants such as epinephrine may induce ventricular fibrillation. ===================== Ecological Information ===================== Ecological:ECOTOXICITY DATA: FISH TOXICITY: 8800 ug/L 96 hour(s) LC50 (Mortality) Guppy (Poecilia reticulata) INVERTEBRATE TOXICITY: 3600 ug/L 24 hour(s) EC50 (Immobilization) Water flea (Daphnia magna) ALGAL TOXICITY: 4400 ug/L 8 hour(s) EC50 (Growth) Green algae (Selenastrum capricornutum) ==================== Disposal Considerations ==================== Waste Disposal Methods:Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): U239. Dispose in accordance with all applicable regulations. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: Xylenes ID NUMBER: UN1307 HAZARD CLASS OR DIVISION: 3 PACKING GROUP: II LABELING REQUIREMENTS: Flammable liquid ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes REACTIVE: No SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40 CFR 372.65): p-Xylene Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): p-Xylene: 100LBSRQ OSHA PROCESS SAFETY (29CFR1910.119): Not regulated. State Regulatory Information: California Proposition 65: Not regulated. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.