ASHLAND CHEMICAL CO. -- HEXANE -- 8040-00-853-8913
===================== Product Identification ===================== Product ID:HEXANE MSDS Date:11/13/1992 FSC:8040 NIIN:00-853-8913 === Responsible Party === Company Name:ASHLAND CHEMICAL CO. Box:2219 City:COLUMBUS State:OH ZIP:43216 Country:US Info Phone Num:614-889-3333 Emergency Phone Num:800-274-5263 CAGE:5A188 === Contractor Identification === Company Name:ASHLAND CHEMICAL CO Address:5200 PAUL BLAZEL MEMORIAL PARKWAY Box:City:DUBLIN State:OH ZIP:43017 Country:US Phone:614-889-4505 CAGE:5A188 Company Name:CHEMICAL COMMODITIES AGENCY, INC. Address:27447 PACIFIC STREET Box:City:HIGHLAND State:CA ZIP:92346-2640 Country:US Phone:909-864-2310 CAGE:60777 ============= Composition/Information on Ingredients ============= Ingred Name:HEXANE (NIOSH: 100 PPM - 8 HR TWA, 510 PPM CEILING, LIMITS ARE FOR N-HEXANE.PEL/TLV FOR OTHER ISOMERS OF HEXANE 500 PPM) CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: >95% Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:EYE:IRRITATION (BURNING,TEARING,REDNESS). SKIN:IRRITATION. PROLONGED:DRY SKIN (REDNESS,BURNING,DRYING,CRACKING SKIN & SKIN BURNS). INHAL:NASAL & RESPRTRY IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS (DI ZZINESS,WEAK,FATIGUE,NAUSEA,HEADACHE,UNCONSCIOUSNESS,DEATH). INGEST:GI IRRITATION (NAUSEA,VOMIT,DIARRHEA)ASPIRATION HZD. Effects of Overexposure:N/K CHRONIC: PERIPHERAL NERVE TISSUE DAMAGE (ARMS & LEGS), MUSCULAR WEAKNESS, LOSS OF SENSATION IN EXTREMITIES (PERIPHERAL NEUROPATHY), POTENTIATE (SPEED ONSET) PERIPHERAL NEUROPATHY. KIDNEY DAMAGE. ======================= First Aid Measures ======================= First Aid:SKIN: REMOVE CONTAM CLOTHING.WASH EXPOSED AREA W/SOAP & WATER.IF SYMPTOMS PERSIST,GET MED AID. EYE: IF SYMPTOMS DEVELOP,MOVE TO FRESH AIR.FLUSH EYES W/CLEAN WATER HOLDING EYELIDS APART.IF SYMPTOMS PER SIST,GET MED AID. INGEST: DON'T INDUCE VOMIT.KEEP WARM,QUIET,GET MED AID. INHAL:REMOVE TO FRESH AIR.IF BREATHING DIFFICULT,GIVE OXYGEN.IF BREATHING STOPPED,GIVE ARTIF RESP.KEEP WARM,QUIET,GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point:-10F,-23C Lower Limits:1.0 Extinguishing Media:REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING FIRES. Unusual Fire/Explosion Hazard:HIGHLY VOLATILE,READILY GIVES OFF VAPOR-MAY TRAVEL ALONG GROUND/MOVED BY VENT/IGNITD FAR FROM HANDLING PT.NEVER WELD/CUT ON/NEAR DRUM.GRND/BOND 5/5+ METAL CNTNR ================== Accidental Release Measures ================== Spill Release Procedures:SMALL:ABSORB LIQ ON VERMIC,FLOOR ABSORBENT,ETC & TRANSFR TO HOOD. LRG:ELIMINATE IGNITN SOURCE.EXCLUDE PERSON NOT WEARING PROTECT EQUIP.STOP SPILL AT SOURCE.PREVENT FROM ENTERING DRAINS,SEWERS,STREAMS, WATERBODIES.NOTIFY AUTHORITIES IF OCCURS. * Neutralizing Agent:N/K * PUMP OR VACUUM TRANSFER SPILLED PRODUCT TO CLEAN CNTNRS FOR RECOVERY. ** ====================== Handling and Storage ====================== Handling and Storage Precautions:CONTAINERS OF MATERIAL MAY BE HAZARDOUS WHEN EMPTIED, AS EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR,LIQUID,SOLID)OBEY HZD PRECAUTIONS IN MSDS. Other Precautions:HYDROCARBON SOLVENTS ARE BASICALLY NON-CONDUCTORS OF ELECTRICITY & CAN BECOME ELECTROSTATICALLY CHARGED DURING MIXING,FILTERING,PUMPING AT HIGH FLOW RATES. IF CHARGE REACHES HIGH LEVEL, SPARKS CAN FOR M THAT MAY IGNITE FLAMMABLE LIQUID VAPOR ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT OF PRODUCT/COMPONENT EXCEEDED, NIOSH/MSHA AIR SUPPLIED RESPIRATOR ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATOR (NEG PRESSURE) UNDER SPECIFIED CONDITION # Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURES BELOW TLV(S). Protective Gloves:RESISTANT GLOVES (SEE SFTY EQUIP MFR) Eye Protection:CHEMICAL SPLASH GOGGLES ADVISED Other Protective Equipment:TO PREVENT REPEATED OR PROLONGED SKIN CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS. Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health # (SEE YOUR SAFETY EQUIPMENT SUPPLIER). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:149 TO 158F Vapor Pres:125 @ 68F Vapor Density:3.0 Spec Gravity:0.672-0.684 Evaporation Rate & Reference:9.00 (N-BU AC=1) Appearance and Odor:CLEAR SAYBOLT COLOR #30 LIQUID Percent Volatiles by Volume:100.00 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENT Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS: CARBON DIOXIDE AND CARBON MONOXIDE, VARIOUS HYDROCARBONS, ETC. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. ** ABSORB UNRECOVERABLE PRODUCT. TRANSFER CONTAMINATED ABSORBENT, SOIL & OTHER MATERIALS TO CNTNRS FOR DISPOSAL. 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