MATHESON TRI-GAS, INC. -- N-PROPYL ACETATE -- -
===================== Product Identification ===================== Product ID:N-PROPYL ACETATE MSDS Date:Jan 24 1989 Kit Part:=== Responsible Party === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 Chemtrec Ind/Phone:18004249300 === Contractor Identification === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST Box:City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. Address:530 WATSON STREET Box:City:WHITBY State:ZIP:L1N 5R9 Country:ONTARIO, CANADA Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:N-PROPYL ACETATE CAS:109-60-4 Fraction by Wt: 100.0% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:No OSHA:No Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: irritation, nausea, vomiting, difficulty breathing, headache, symptoms of drunkenness LONG TERM EXPOSURE: same as effects reported in short term exposure SKIN CONTACT: SHORT TERM EXPOSURE: mild irritation LONG TERM EXPOSURE: no information on significant adverse effects EYE CONTACT: SHORT TERM EXPOSURE: irritation, tearing LONG TERM EXPOSURE: no information on significant adverse effects INGESTION: SHORT TERM EXPOSURE: same as effects reported in short term inhalation, vomiting, digestive disorders, symptoms of drunkenness LONG TERM EXPOSURE: no information is available Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention. ===================== Fire Fighting Measures ===================== Flash Point:55 F (13 C) (CC) Lower Limits:1.7% @ 38 C Upper Limits:8% Extinguishing Media:alcohol resistant foam, carbon dioxide, regular dry chemical, water Large fires: Use alcohol-resistant foam or flood with fine water spray. Fire Fighting Procedures:Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation radius: 800 meters (1/2 mile). Unusual Fire/Explosion Hazard:Severe fire hazard. Severe explosion hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. ================== Accidental Release Measures ================== Spill Release Procedures:Avoid heat, flames, sparks and other sources of ignition. Remove sources of ignition. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind and keep out of low areas. Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. Keep separated from incompatible substances. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. 1700 ppm Any supplied-air respirator. Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. Any powered, air-purifying respirator with a full facepiece and organic vapor cartridge(s). Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. Escape - Any air-purifying respirator with a full facepiece and an organic vapor canister. Any appropriate escape-type, self-contained breathing apparatus. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. Protective Gloves:Wear appropriate chemical resistant gloves. Eye Protection:Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:Wear appropriate chemical resistant clothing. Supplemental Safety and Health N-PROPYL ACETATE: 200 ppm (840 mg/m3) OSHA TWA 250 ppm (1040 mg/m3) OSHA STEL (vacated by 58 FR 35338, June 30, 1993) 200 ppm ACGIH TWA 250 ppm ACGIH STEL 200 ppm (840 mg/m3) NIOSH recommended TWA 10 hour(s) 250 ppm (1050 mg/m3) NIOSH recommended STEL ================== Physical/Chemical Properties ================== Boiling Pt:216 F (102 C) Melt/Freeze Pt:-139 F (-95 C) Vapor Pres:40 mmHg @ 29 C Vapor Density:3.5 Spec Gravity:0.9 pH:Not available Evaporation Rate & Reference:Not available Solubility in Water:2% Appearance and Odor:PHYSICAL STATE:liquid COLOR:colorless ODOR:fruity odor Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:Stable at normal temperatures and pressure. Stability Condition to Avoid:Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Hazardous Decomposition Products:Thermal decomposition products: miscellaneous decomposition products Thermal decomposition products: miscellaneous decomposition products Conditions to Avoid Polymerization:Will not polymerize. =================== Toxicological Information =================== Toxicological Information:N-PROPYL ACETATE: IRRITATION DATA: 500 mg open skin-rabbit mild; 500 mg/24 hour(s) eyes-rabbit mild TOXICITY DATA: >20 ml/kg skin-rabbit LD50; 9370 mg/kg oral-rat LD50 LOCAL EFFECTS: Irritant: inhalation, eye ACUTE TOXICITY LEVEL: Slightly Toxic: ingestion TARGET ORGANS: central nervous system MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: kidney disorders, respiratory disorders, skin disorders and allergies ADDITIONAL DATA: Alcohol may enhance the toxic effects. ===================== Ecological Information ===================== Ecological:ECOTOXICITY DATA: FISH TOXICITY: 60000 ug/L 96 hour(s) LC50 (Mortality) Fathead minnow (Pimephales promelas) INVERTEBRATE TOXICITY: 625 mg/L 24 hour(s) EC100 (Abundance) Water flea (Daphnia magna) ALGAL TOXICITY: 26000 ug/L NR year(s) (Population Growth) Green algae (Scenedesmus quadricauda) ==================== Disposal Considerations ==================== Waste Disposal Methods:Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: n-Propyl acetate ID NUMBER: UN1276 HAZARD CLASS OR DIVISION: 3 PACKING GROUP: II LABELING REQUIREMENTS: Flammable liquid ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes REACTIVE: No SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40 CFR 372.65): Not regulated. Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY (29CFR1910.119): Not regulated. State Regulatory Information: California Proposition 65: Not regulated. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.