FISHER SCIENTIFIC -- PENTANE -- 6810-00-070-0891
===================== Product Identification ===================== Product ID:PENTANE MSDS Date:12/30/1992 FSC:6810 NIIN:00-070-0891 === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:PENTANE CAS:109-66-0 RTECS #:RZ9450000 Fraction by Wt: 99.2% OSHA PEL:1000 PPM ACGIH TLV:600 PPM/750STEL;9596 Ingred Name:SUPDAT:SOUND FROM VENTING SAFETY DEVICE/ANY DISCOLORATION OF TANK DUE TO FIRE. ISOLATE FOR 1/2 MILE IN ALL (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: DIRECTIONS IF TANK, RAIL CAR OR TANK TRUCK IS INVOLVED IN FIRE. RTECS #:9999999ZZ Ingred Name:EXPLO HAZ: AS FAR A DISTANCE AS POSS. AVOID BRTHG TOX VAP, KEEP UPWIND. EVAPORATE TO A RADIUS OF 1500 FEET FOR (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: UNCONTROLLABLE FIRES. CONSIDER EVACUATION OF DOWNWIND AREA IF MATERIAL IS LEAKING. RTECS #:9999999ZZ Ingred Name:CNDTNS (STAB): MAY VIOLENTLY RUPTURE IN HEAT OR FIRE. AVOID CONTAMINATION OF WATER SOURCES. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: OCCAS LIFTING UPPER & LOWER LIDS, UNTIL NO EVID OF CHEM REMAINS AT LEAST 15 MIN. GET MED ATTN (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: IMMED. INGEST: EXTREME CARE MUST BE USED TO PVNT ASPIR. USE GASTRIC LAVAGE W/ACTIVATED CHARCOAL & CUFFED (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: ENDOTRACHEAL TUBE W/IN 15 MIN. IN THE ABSENCE OF DEPRESS/CONVL/IMPAIRED GAG FLEX, IPECAC EMESIS CAN BE (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: DONE. WHEN VOMIT BEGINS, KEEP HEAD LOWER THAN HIPS TO PVNT ASPIRATION. AFTER VOMIT STOPS, GIVE 30-60 (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:MILLILITERS OF FLEET'S PHOSPHO-SODA DILUTED 1:4 IN H*2O. MAINTAIN AIRWAY, BLOOD PRESS & RESP. (DREISBACH (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: HANDBOOK OF POISONING, 11TH ED.) TREATMENT MUST BE ADMINISTERED BY QUALIFIED MED PERS. GET MED ATTN. (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: ANTIDOTE: NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. RTECS #:9999999ZZ Ingred Name:SPILL PROC: NO SMOKING, FLAMES/FLARES IN HAZ AREA. KEEP UNNECESSARY PEOPLE AWAY; ISOLATE HAZARD AREA & RESTRICT ENTRY. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:DOGS. EXPOSED RATS DEVELOPED NEUROHISTOLOGICAL STRUCTURAL CHANGES IN THE DEVELOPING CEREBRAL (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:CORTEX. SKIN:BRIEF CNTCT MAY CAUSE MILD IRRIT. 1 HR CNTCT W/UNDILUTED LIQ HAS CAUSED ITCHING, ERYTHEMA, (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: PIGMENTATION, SWELLING, BURNING, & PAIN. 5 HR EXPOS HAS CAUSED BLISTERS. EYE: CNTCT W/VAPS/LIQ MAY (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:CAUSE REDNESS & PAIN. INGEST:MAY CAUSE ABDOM PAIN & NAUSEA. IF LARGE AMTS OF ALIPHATIC HYDROCARBONS ARE (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: INGESTED & RETAINED, CNS DEPRESSION MAY OCCUR. ASPIRATION MAY RESULT IN ASPHYXIA & BRAIN DAMAGE, CHEM (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: PNEUM, PULM EDEMA, CARDIAC ARREST, & DEATH. CHRONIC: INHAL: 5 WORKERS EXPOSED TO SOLV WHICH AS 80% (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: PENTANE, 14% HEPTANE, & 5% HEXANE DEVELOPED POLYNEUROPATHY. 3 OF THE 5 EXPERIENCED ANOREXIA, ASTHENIA, (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21: PARESTHESIA, FATIGUE, & BILATERAL MUSCLE FAILURE, MOSTLY IN THE LEGS. IN MICE, PENTANE HAS CAUSED (ING 23) RTECS #:9999999ZZ Ingred Name:ING 22:ANOXEMIA. RATS EXPOSED TO 3000 PPM FOR 12 HRS A DAY, 5 DAYS A WEEK FOR 16 WEEKS, OR TO 3000 PPM FOR 9 HRS(ING 24) RTECS #:9999999ZZ Ingred Name:ING 23: A DAY, 5 DAYS A WEEK, FOR 30 WEEKS SHOWED NO SIGNS OF NEUROTOXICITY. SKIN:PRLNG/RPTD EXPOS MAY CAUSE (ING 25) RTECS #:9999999ZZ Ingred Name:ING 24: DRYING, CRACKING, AND DERMATITIS. EYE: REPEATED/PROLONGED EXPOSURE TO IRRITANTS MAY CAUSE CONJUNCTIVITIS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL:IRRIT/NARCOTIC. 15000 PPM IMMED DANGEROUS TO LIFE/HLTH. HUMAN EXPOS TO 5000 PPM FOR 10 MIN RSLTD IN NO IRRIT/SYSTEMIC EFTS. CONCS > 5000 PPM MAY CAUSE IRRIT OF THE NOSE & THROAT, EXHILARATION, H DCH, DIZZ, DROW, & DFCLTY IN BRTHG. VERY HIGH CONCS MAY CAUSE NAUSEA, CONFUSION, A PERSISTENT (EFTS OF OVEREXPOSURE) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:TASTE OF GASOLINE, INCOORDINATION, UNCON, & IF SUFFICIENT OXYGEN IS DISPLACED, ASPHY. MICE EXPOSED TO 32000-64000 PPM FOR 5 MIN SHOWED SIGNS OF RESP IRRIT & LIGHT ANESTH; 90000-120000 PPM FOR 5-60 MIN PRDCED NARCOSIS; & 128000-129000 PPM HAS BEEN FATAL IN 5-37 MIN. IT IS A WEAK CARDIAC SENSITIZER IN (ING 15) Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR IMPAIRED PULMONARY FUNCTION. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. IF BRTHG HAS STOPPED, PERFORM ARTF RESP. KEEP PERS WARM & AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET MED ATTN IMMED. SKIN:REMOVE CONTD CLTHG & SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LRG AMTS OF H*2O UNTIL NO EVID OF CHEM REMAIN (APPROX 15-20 MIN). GET MED ATTN IMMED. EYE:WASH IMMED W/LRG AMTS OF H*2O/NORMAL SALINE, (ING 7) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:<-40F,<-40C Lower Limits:1.4% Upper Limits:7.8% Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5). Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . (1990 EMER RESPONSE GUIDEBOOK, DOT P 5800.5). MOVE CNTNR FROM FIRE AREA IF YOU CAN DO IT W/OUT RISK. (SUPDAT) Unusual Fire/Explosion Hazard:EXTING ONLY IF FLOW CAN BE STOPPED; USE H*2O IN FLOODING AMTS AS FOG, SOLID STREAMS MAY NOT BE EFTIVE. COOL CNTNRS W/FLOODING QTYS OF H*2O, APPLY FROM (ING 4) ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF IGNITION SOURCES. STOP LEAK IF YOU CAN DO IT W/OUT RISK. USE H*2O SPRAY TO REDCE VAP. FOR SMALL SPILLS, TAKE UP W/SAND/OTHER ABSORB MATL & PLACE INTO CNTNRS FOR LATER DISP. FOR LRGR SPILLS, D IKE FAR AHEAD OF SPILL FOR LATER DISP. (ING 14) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:CLOTHING: EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE (IMPERVIOUS CLOTHING & EQUIPMENT TO PREVENT REPEATED/PROLONGED SKIN CONTACT WITH THIS SUBSTANCE. Other Precautions:EMERGENCY EYE WASH: WHERE THERE IS ANY POSSIBILITY THAT AN EMPLOYEE'S EYES MAY BE EXPOSED TO THIS SUBSTANCE, THE EMPLOYER SHOULD PROVIDE AN EYE WASH FOUNTAIN WITHIN THE IMMEDIATE WORK AREA FOR EMERGEN CY USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:THE SPECIFIC RESP SELECTED MUST BE BASED ON CONTAMINATION LEVELS FOUND IN THE WORK PLACE, MUST NOT EXCEED THE WORKING LIMITS OF THE RESPIRATOR & BE APPROVED BY NIOSH. FOR A LIST OF SPECIFIC RESPS RECO MMENDED CONTACT NEHC . Ventilation:PROVIDE LOCAL EXHAUST/GENERAL DILUTION VENT TO MEET PUBLISHED EXPOSURE LIMITS. VENT EQUIPMENT MUST BE EXPLOSION-PROOF. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC:APPLY COOLING H*2O TO SIDES OF CNTNRS THAT ARE EXPOSED TO FLAMES UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM ENDS OF TANKS. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER/MO NITOR NOZZLES; IF THIS IS IMPOSSIBLE, WITHDRAW FROM AREA & LET FIRE BURN. WITHDRAW IMMED IN CASE OF RISING (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:97.0F,36.1C Melt/Freeze Pt:M.P/F.P Text:-202F,-130C Vapor Pres:400 @18.5C Vapor Density:2.5 Spec Gravity:0.626 Evaporation Rate & Reference:28.6 (BUTYL ACETATE = 1) Solubility in Water:0.04% Appearance and Odor:COLORLESS LIQUID WITH GASOLINE-LIKE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES PENTANE: OXIDIZERS (STRONG): FIRE AND EXPLOSION HAZARD. PLASTICS, RUBBER, AND COATINGS: MAY ATTACK SOME FORMS. Stability Condition to Avoid:AVOID CNTCT W/HEAT, SPARKS, FLAMES/OTHER SOURCES OF IGNITION. VAPS MAY BE EXPLO. AVOID OVERHEATING OF CNTNRS; (ING 6) Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF CARBON. Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.