COLONIAL TERMINALS INC -- DIESEL FUEL -- 9140-00N073123
===================== Product Identification ===================== Product ID:DIESEL FUEL MSDS Date:11/23/1993 FSC:9140 NIIN:00N073123 === Responsible Party === Company Name:COLONIAL TERMINALS INC Address:N LATHROP AVE Box:576 City:SAVANNAH State:GA ZIP:31402-0576 Country:US Info Phone Num:912-236-1331 Emergency Phone Num:912-236-1331 Preparer's Name:J.W. GRIFFIN CAGE:8E236 === Contractor Identification === Company Name:COLONIAL TERMINALS INC Address:N LATHROP AVE Box:576 City:SAVANNAH State:GA ZIP:31402-0576 Country:US Phone:912-236-1331 CAGE:8E236 ============= Composition/Information on Ingredients ============= Ingred Name:GAS OIL, BLEND; (STRAIGHT RUN MIDDLE DISTILLATES) CAS:64741-44-2 RTECS #:LX3296000 Fraction by Wt: 70-100% OSHA PEL:400 PPM (MFR) ACGIH TLV:N/K Ingred Name:DISTILLATES (PETROLEUM), LIGHT CATALYTIC CRACKED; (LIGHT CATALYTIC CRACKED DISTILLATE) CAS:64741-59-9 RTECS #:JN9385000 Fraction by Wt: 0-30% OSHA PEL:400 PPM (MFR) ACGIH TLV:N/K Ingred Name:NAPHTHA, HEAVY STRAIGHT RUN; (NAPHTHALENE) CAS:64741-41-9 Fraction by Wt: <3% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:SUPDAT:UNCON, CONVLS, RESP COLLAPSE & DEATH. INGEST: ASPIR HAZ--MATL CAN ENTER LUNGS DURING SWALLOW/VOMIT & CAUSE(ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: INFLAMM & DMG. INGEST OF EXCESS QTYS OF MATL MAY CAUSE IRRIT OF DIGEST TRACT & SIGNS OF NERVS SYS DEPRESS (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: (EG HDCH, DROW, DIZZ, LOSS OF COORDINATION & FATG). PROD CNTNS MIX OF PETRO HYDROCARBS CALLED MID DISTILS (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: (THEY BOIL BETWEEN APPROX 350F-700F). BECAUSE OF BROAD DESCRIPTION, MANY PRODS ARE CONSIDERED MID DISTLS (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: YET THEY ARE PRDCED BY VARIETY OF DIFFERENT PETRO REFINING PROCESSES. TOXICOLOGY DATA ON SOME MID DISTILS (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: FOUND THEY CAUSED POS RESPONSES IN SOME MUTAGENICITY TESTS & SKIN CANCER WHEN RPTDLY APPLIED TO MICE OVER(ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: THEIR LIFETIME. PROD MAY CONTAIN SOME MID DISTLS FOUND TO CAUSE THOSE ADVERSE EFFECTS. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: OF EXPOS DEVELOP, MOVE AWAY FROM SOURCE OF EXPOS & INTO FRESH AIR. IF SYMPS PERSIST, SEEK IMMED (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:MED ATTN. IF NOT BRTHG, IMMED BEGIN ARTF RESP. IF BRTHG DFCLTY DEVELOPS, O*2 SHOULD BE ADMIN BY QUALIFIED(ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:PERS. SEEK IMMED MED ATTN. INGEST: ASPIR HAZ--DO NOT INDUCE VOMIT OR GIVE ANYTHING BY MOUTH BECAUSE MATL(ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:CAN ENTER LUNGS & CAUSE SEV LUNG DMG. IF VICTIM IS DROWSY/UNCON, PLACE ON SIDE W/HEAD DOWN. IF POSS, DO (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: NOT LEAVE UNATTENDED. SEEK MED ATTN. NOTE TO MD: EXPOS TO HIGH CONCS OF MATL (EG IN ENCLSD SPACES/WITH (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: DELIB ABUSE) MAY BE ASSOC W/CARD ARRHYS. EPINEPHRINE & OTHER SYMPATHOMIMETIC DRUGS MAY INITIATE CARDIAC (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: ARRHYS IN PERS EXPOSED TO MATL. OTHER DRUGS W/LESS ARRHYTHMOGENIC POTNTL SHOULD BE CONSIDERED. IF (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: SYMPATHOMIMETIC DRUGS ARE ADMINISTERED, OBSERVE FOR DEVELOPMENT OF CARDIAC ARRHYTHMIAS. RTECS #:9999999ZZ Ingred Name:SPILL PROC: SPILLED MATL. STAY UPWIND & AWAY FROM SPILL. ISOLATE AREA & RESTRICT ENTRY TO EMER RESPONSE PERS. (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: STOP SPILL/RELS IF IT CAN BE DONE SAFELY. WEAR APPROP PROT EQUIP AS CNDTNS WARRANT. PVNT SPILLED MATL (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:FROM ENTERING SEWERS, STORM DRAINS & ANY WATERWAY. USE SAND, SOIL OR OTHER INERT MATL TO DIKE & CNTN LIQ.(ING 22) RTECS #:9999999ZZ Ingred Name:ING 21: LIQ MAY BE RECOVERED BY PUMPING UP. REMAINING MATL, IE SAND, CONTAMD DIRT, SORBENT MATL MUST BE PICKED (ING 23) RTECS #:9999999ZZ Ingred Name:ING 22; UP OR EXCAVATED & DISPOSED OF I/A/W FEDERAL, STATE & LOCAL HAZ WASTE MANAGEMENT REGULATIONS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES: MAY CAUSE MILD IRRIT. DIRECT CNTCT W/LIQ OR EXPOS TO VAPS/MISTS MAY CAUSE STINGING, TEARING & REDNESS. SKIN: MAY CAUSE MILD IRRIT. PRLNGD/RPTD CNTCT MAY CAUSE REDNESS, BURNING & DRYING & CRACKIN G OF SKIN. SYMPS MAY ALSO INCL PAIN/FEELING OF HEAT, DISCOLORATION, SWELL & BLISTERING. CNTCT MAY RSLT (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:IN SKIN ABSORPTION BUT SYMPS OF TOX ARE NOT ANTIC BY THIS ROUTE ALONE UNDER NORM CNDTNS OF USE. PERS W/PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO EFTS OF MATL. INHAL:WHILE MATL HA S LOW DEGREE OF TOX, BRTHG HIGH CONCS OF VAPS/MISTS MAY CAUSE FLUSHING, BLURRED VISION, NAUS & SIGNS OF NERVS (SUPDAT) Medical Cond Aggravated by Exposure:RESPIRATORY SYMPTOMS ASSOCIATED WITH PRE-EXISTING LUNG DISORDERS (EG ASTHMA-LIKE CONDITIONS) MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:EYE:IF IRRIT/REDNESS DEVELOPS, MOVE VICTIM AWAY FROM EXPOS & INTO FRESH AIR. FLUSH EYES W/CLEAN WATER FOR AT LEAST 15 MIN. IF SYMPS PERSISTS, SEEK MED ATTN. SKIN:WIPE MATL FROM SKIN & REMOVE CONTAMD S HOES & CLTHG. CLEANSE AFFECTED AREA THORO BY WASHING W/MILD SOAP & WATER & IF NEC WATERLESS SKIN CLEANSER. IF IRRIT/REDNESS DEVELOPS & PERSISTS, SEEK MED ATTN. INHAL:IF RESP SYMPS/OTHER SYMPS (ING 11) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:125F,52C Lower Limits:0.6% Upper Limits:7.5% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM. WATER FOG MAY BE EFFECTIVE IN SMALL INCIPIENT FIRES. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . STRAIGHT WATER STREAMS MAY SPREAD FLAM LIQ. WATER STREAMS SHOULD BE USED TO COOL EXPOSED CNTNRS & SURFS.(SUPDAT) Unusual Fire/Explosion Hazard:LIQ EVAPS & FORMS VAP (FUMES) WHICH CAN CATCH FIRE & BURN W/EXPLO VIOLENCE. INVISIBLE VAP SPREADS EASILY & CAN BE SET ON FIRE BY MANY SOURCES SUCH AS (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REPORT SPILLS/RELS TO APPROP AUTHS I/A/W FED, STATE & LOC REGS. US COAST GUARD REGS REQ IMMED REPORTING OF ANY SPILL THAT ENTERS/THREATENS TO ENTER ANY WATERWAY. KEEP ALL SOURCES OF IGNIT, SPKS, FLAME S, OPEN LIGHTS &/OR HOT SURFS AWAY FROM(ING 19) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:CAUTION: NO SMOKING OR OPEN FLAMES. KEEP AWAY FROM HEAT, SPARKS, FLAMES OR OTHER SOURCES OF IGNITION. Other Precautions:EXCESSIVE EXPOSURE MAY CAUSE IRRITATION TO EYES, SKIN OR RESPIRATORY SYSTEM. AVOID LIQUID, MIST OR VAPOR CONTACT. HARMFUL OR FATAL IF SWALLOWED. ASPIRATION HAZARD - CAN ENTER LUNGS AND CAUSE DAMAGE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:THE USE OF NIOSH APPRVD RESP PROT IS ADVISED WHEN CONCS EXCEED THE ESTABLISHED EXPOS LIMS. DEPENDING ON AIRBORNE CONC, USE A NIOSH APPRVD RESP OR GAS MASK W/APPROP CARTRIDGES & CANISTERS OR NIOSH APPR VD SUPPLIED AIR EQUIPMENT. Ventilation:IF CURRENT VENT PRACTS ARE NOT ADEQ TO MAINTAIN AIRBORNE CONCS BELOW ESTAB EXPOS LIMS, ADDNL VENT/EXHST SYS MAY BE REQD. Protective Gloves:IMPERMEABLE GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . IMPERVIOUS CLOTHING SHOULD BE WORN AS NEEDED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC:PVNT ANY RUNOFF FROM ENTERING SEWERS/WATERWAYS. EXPLO HAZ:PILOT LIGHTS, WELDING EQUIP & ELEC MOTORS & SWITCHES. FIRE HAZ IS GREATER AS LIQ TEMP RISES ABOVE 85F. EFTS OF OVEREXP:SYS DEP RESS (MAY INCL HDCH, DROW, DIZZ, LOSS OF APPETITE/COORDINATION, WEAKNESS & FATG). EXPOS TO HIGH CONCS MAY CAUSE (ING 4) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>350F,>177C Vapor Pres:1 @ 20C Vapor Density:>1 Spec Gravity:0.9 Solubility in Water:INSOLUBLE Appearance and Odor:BROWNISH BLUE GREEN LIQUID; KEROSENE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID STRONG OXIDIZING AGENTS (PEROXIDE, PERMANGANATE, DICHROMATE, CHLORINE, ETC), STRONG ACIDS, CAUSTICS & HALOGENS. Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, STATIC ELECTRICITY OR ANY OTHER POTNTL IGNIT SOURCES SHOULD BE AVOIDED. PVNT VAPOR ACCUM. Hazardous Decomposition Products:COMBUSTION MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE AND REACTIVE HYDROCARBONS (ALDEHYDES, AROMATICS, ETC). ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL HAZARDOUS WASTE MANAGEMENT REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.