MALLINCKRODT INC. SCIENCE PRODUCTS DIV. -- PYROCATECHOL -- 6810-00-246-6276
===================== Product Identification ===================== Product ID:PYROCATECHOL MSDS Date:11/09/1992 FSC:6810 NIIN:00-246-6276 === Responsible Party === Company Name:MALLINCKRODT INC. SCIENCE PRODUCTS DIV. Box:800 City:PARIS State:KY ZIP:40362 Country:US Info Phone Num:314-539-1600 Emergency Phone Num:314-539-1600 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:CATECHOL; PYROCATECHOL CAS:120-80-9 RTECS #:DJ3450000 Other REC Limits:5 PPM OSHA PEL:5 PPM ACGIH TLV:2320 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 260 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: DIGESTIVE DISTURBANCES. INGESTION: POISONOUS. POSSIBLY DEATH. SKIN: CORROSIVE. ABSORPTION W/SYSTEMIC POISONING EFFECTS TO FOLLOW. DISCOLORATION & SEVERE BURNS. EYES: CORROSIVE. SEVERE DAMA GE & BLINDNESS. REPEATED EXPOSURE MAY CAUSE LIVER, KIDNEY & NEUROLOGICAL DISORDERS. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: VOMITING, DIFFICULT IN SWALLOWING, DIARRHEA, LOSS OF APPETITE. INGESTION: BURNING PAIN IN MOUTH & THROAT, ABDOMINAL PAIN, HEADACHE, DIZZINESS, MUSCULAR WEAKNESS, IRREGULAR BREATHING, COMA & POSSIBLY DEATH. SKIN: DISCOLORATION &SEVERE BURNS. EYES: REDNESS, PAIN, BLURRED VISION. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER OR KIDNEY FUNCTION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NECESSARY. INGESTION: INDUCE VOMITING IMMEDIATELY BY GIVING 2 GLASSES OF WATER & STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH TO AN UNC ONSCIOUS PERSON. SKIN: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS WHILE REMOVING CONTAMINATED CLOTHING & SHOES. EYES: WASH W/PLENTY OF WATER FOR AT LEAST 15 MINS. OBTAIN MED ATTN IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:137C/279F Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM OR CO2 Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & NIOSH APPROVED SCBA W/FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:FINE DUST DISPERSED IN AIR IN SUFFICIENT CONCENTRATIONS & IN THE PRESENCE OF AN IGNITION SOURCE IS A POTENTIAL DUST EXPLOSION. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. VENTILATE AREA. WEAR PROTECTIVE EQUIPMENT. CLEAN UP IN A MANNER THAT DOES NOT DISPERSE DUST INTO THE AIR. USE NON-SPARKING TOOLS. PICK UP SPILL FOR RECOVERY OR DISPOSAL & PLAC E IN A CLOSED CONTAINER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. ISOLATE FROM INCOMPATIBLE SUBSTANCES. Other Precautions:AVOID CONTACT W/EYES, SKIN, CLOTHING & BREATHING OF DUST. USE W/ADEQUATE VENTILATION. DON'T WEAR CONTACT LENSES WHEN WORKING W/THIS MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED, USE A NIOSH APPROVED DUST/MIST RESPIRATOR. ALTERNATIVELY, A SUPPLIED AIR FULL FACEPIECE RESPIRATOR OR AIRLINED HOOD MAY BE WORN. Ventilation:LOCAL &/OR GENERAL EXHAUST TO KEEP BELOW TLV. Protective Gloves:IMPERVIOUS Eye Protection:CHEMICAL SAFETY GOGGLES/FULL FACE SHIELD Other Protective Equipment:BOOTS, LAB COAT, APRON, COVERALLS, EYE WASH FOUNTAIN & QUICK DRENCH FACILITIES IN WORK AREA. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:245C (473F) Melt/Freeze Pt:M.P/F.P Text:219-223F Vapor Pres:10 Vapor Density:3.79 Spec Gravity:1.344 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS CRYSTALS W/FAINT CHARACTERISTIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACID CHLORIDES, ACID ANHYDRIDES, BASES, OXIDIZING AGENTS. Stability Condition to Avoid:ELEVATED TEMPS OR OTHER SOURCES OF IGNITION, AIR, LIGHT Hazardous Decomposition Products:CO2 & CO ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY MAY BE BURNED IN AN APPROVED INCINERATOR OR DISPOSED OF IN AN APPROVED WASTE FACILITY. REPORTABLE QUANTITY: 1 LB. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERA L REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.