ELIAS USA INC -- SODIUM AZIDE -- 6810-00F056235
===================== Product Identification ===================== Product ID:SODIUM AZIDE MSDS Date:04/03/1993 FSC:6810 NIIN:00F056235 === Responsible Party === Company Name:ELIAS USA INC Address:373 280TH ST City:OSCEOLA State:WI ZIP:54020-5000 Country:US Info Phone Num:715-294-2144/800-583-5427 Emergency Phone Num:715-294-2144/800-583-5427 CAGE:04XG4 === Contractor Identification === Company Name:ELIAS USA INC Address:373 280TH ST City:OSCEOLA State:WI ZIP:54020-5000 Country:US Phone:715-294-2144/800-583-5427 CAGE:04XG4 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM AZIDE, AZIDE *98-1* CAS:26628-22-8 RTECS #:VY8050000 Other REC Limits:0.1 PPM ACGIH TLV:C 0.29 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 27 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION TO THE RESPIRATORY TRACT & MUCOUS MEMBRANES/ABSORPTION. INGESTION: HIGHLY TOXIC, MAY CAUSE DEATH. SKIN: HIGHLY TOXIC, IRRITATION/ABSORPTION. EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION/SORE THROAT/COUGHING/DIZZINESS/SHORTNESS OF BREATH/FAINTING/BREATHLESSNESS/RAPID HEARTBEAT/NAUSEA/VOMITING/HEADACHE/RESTLESSNESS/DIARRHEA/LOW BLOOD PRESSURE/ABNORMAL BREATHING/REDUCED BODY TEMP/REDUCED BODY PH/CONVULSIONS/COLLAPSE/REDNESS/PAIN/BLURRED VISION. ======================= First Aid Measures ======================= First Aid:INGESTION: INDUCE VOMITING BY GIVING 2 GLASSES OF WATER & STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEED. SKIN/EYES: FLUSH W/PLENTY OF WATER FOR15 MINS. IN CASE OF HEADACHE/DIZZINESS HAVE PATIENT LIE FLAT & KEEP WARM. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, FOAM/CO2. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & NIOSH APPROVED SCBA W/FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND/OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:COMBUSTIBLE SOLID. MAY POSE A FIRE HAZARD UPON HEATING, SHOCK, CONCUSSION/FRICTION. REACTS W/BOTH COPPER & LEAD TO PRODUCE EXPLOSIVE AZIDES. (SEE SUPP) ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK. CLEAN UP PERSONNEL MAY REQUIRE PROTECTIVE CLOTHING & RESPIRATORY PROTECTION FROM DUST. PICKUP & PLACE IN A SUITABLE CONTAINER FOR RECLAMATION/DISPOSAL IN A METHOD THAT DOESN'T GENERATE DUST. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER. STORE IN A COOL, WELL VENTILATED AREA AWAY FROM SOURCES OF HEAT/IGNITION. PROTECT CONTAINER FROM PHYSICAL DAMAGE. Other Precautions:ISOLATE FROM INCOMPATIBLE SUBSTANCES. DON'T GET IN EYES, SKIN/CLOTHING. AVOID FRICTION/ROUGH HANDLING BECAUSE OF FIRE & EXPLOSION HAZARD. KEEP CONTAINER CLOSED & AWAY FROM ACIDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED, A DUST/MIST RESPIRATOR W/CHEMICAL GOGGLES MAY BE WORN, IN GENERAL UP TO TEN TIMES THE TLV. A SUPPLIED AIR FULL FRONTAL FACEPIECE RESPIRATOR/AIRLINED HOOD MAY BE WORN. Ventilation:LOCAL/GENERAL EXHAUST IS RECOMMENDED TO KEEP EXPOSURES BELOW EXPOSURE LIMITS. LOCAL EXHAUST IS PREFERRED. Protective Gloves:IMPERVIOUS Eye Protection:CHEMICAL SAFETY GOGGLES/FULL FACESHIELD Other Protective Equipment:IMPERVIOUS PROTECTIVE CLOTHING, BOOTS, LAB COAT, APRON/COVERALLS, EYE WASH FOUNTAIN & SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health FIRE HZRDS CONT'D: EXPLOSIONS IN LABORATORY PLUMBING CONTAINING THESE MATERIALS IS POSSIBLE. MATERIALS TO AVOID CONT'D: DIMETHYL SULFATE, LEAD, BARIUM, CARBONATE, SULFURIC ACID, WATER & NITRIC ACID. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:572F Spec Gravity:1.85 Solubility in Water:42G/100G Appearance and Odor:COLORLESS CRYSTALS W/CHARACTERISTIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO BENZOYL CHLORIDE/POTASSIUM HYDROXIDE/BROMINE/CARBON DISULFIDE/CHROMYL CHLORIDE/COPPER/DIBROMALONONITRILE. (SEE SUPP) Stability Condition to Avoid:SOURCES OF HEAT/IGNITION. Hazardous Decomposition Products:OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CAN'T BE SAVED FOR RECLAMATION MAY BE DISPOSED IN AN RCRA APPROVED HAZARDOUS WASTE FACILITY, IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T FLUSH TO THE SEWER. CAN FORM EXPLOSIVE MIXTURES. 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