MALLINCKRODT INC SCIENCE PRODUCTS DIVISION -- FERROUS CHLORIDE -- 6810-00-857-7636
===================== Product Identification ===================== Product ID:FERROUS CHLORIDE MSDS Date:04/06/1989 FSC:6810 NIIN:00-857-7636 === Responsible Party === Company Name:MALLINCKRODT INC SCIENCE PRODUCTS DIVISION Address:PARIS BYPASS Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:314-982-5000 Emergency Phone Num:314-982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:FERROUS (II) CHLORIDE TETRAHYDRATE CAS:13478-10-9 RTECS #:NO5600000 Fraction by Wt: >99% OSHA PEL:1 MG/M3 (FE) ACGIH TLV:1 MG/M3 (FE); 8990 ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV 1 MG/M3 SOLUBLE IRON SALTS AS FE Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:MILD IRRITANT OR NUISANCE DUST, LOW TOXICITY IN SMALL QUANTITIES BUT LARGER DOSES MAY CAUSE GASTROINTESTINAL DISTURBANCES, MILD SKIN IRRITATION, MILD EYE IRRITATION. LIVER DAMAGE, COMA AND DEATH FROM IRON POISONING HAVE BEEN RECORDED. Explanation of Carcinogenicity:PRODUCT CONTAINS NO INGREDIENTS CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA. Effects of Overexposure:COUGHING, SNEEZING, NAUSEEA, VOMITING, DIARRHEA, BLACK STOOL, PINK URINE DISCOLORATION, REDNESS/SORENESS ON SKIN, REDDENING/TEARING/POSSIBLE PAIN IN EYES, CRYSTALS MAY BE ABRASIVE. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO EFFECTS OF PRODUCT. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION FOR ANY BREATHING DIFFICULTY. INGESTION: INDUCE VOMITING IMMEDIATELY BY GIVING 2 GLASSES OF WATER AND STICKING FINGER DOWN THROAT. CALL A PHYSICI AN IMMEDIATELY. SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. EYES: WASH WITH PLENTY OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:WEAR FULL PROTECTIVE GEAR AND NIOSH APPROVED, SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE IN PRESSURE DEMAND MODE. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. CLEANUP PERSONNEL MAY REQUIRE PROTECTIVE CLOTHING AND RESPIRATORY PROTECTION FROM DUST. SWEEP UP AND CONTAINERIZE. AVOID DUST DISPERSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. Other Precautions:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST/MIST RESPIRATOR WITH CHEMICAL GOGGLES MAY BE WORN UP TO 10 TIMES THE TLV. ALTERNATIVELY, A SUPPLIED AIR FULL FACEPIECE RESPIRATOR OR AIRLINED HOOD MAY BE WORN. Ventilation:SYSTEM OF LOCAL AND/OR GENERAL EXHAUST TO KEEP EXPOSURES BELOW TLVS. Protective Gloves:RECOMMENDED Eye Protection:CHEMICAL SAFETY GOGGLES Other Protective Equipment:MAINTAIN EYEWASH FOUNTAIN AND QUICK-DRENCH FACILITIES IN WORK AREA. Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT AND BEFORE EATING DRINKING OR SMOKING. Supplemental Safety and Health CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH THIS MATERIAL. ================== Physical/Chemical Properties ================== HCC:T4 Boiling Pt:B.P. Text:1873F,1023C Melt/Freeze Pt:M.P/F.P Text:1238F,670C Vapor Pres:10 Vapor Density:NOT GIVEN Spec Gravity:1.93 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:APPRECIABLE Appearance and Odor:PALE GREEN CRYSTALS, NO ODOR Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:ETHYLENE OXIDE, POTASSIUM, SODIUM ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.